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We report Ge23Sb7S70 chalcogenide ring resonators with up to 8 × 104 quality factors operating around 3.6 µm wavelength fabricated through e-beam lithography. Their rib waveguide geometry can be engineered to support close-to-zero dispersion modes needed for mid-infrared microcomb generation. 

Abstract A novel force sensor exploiting the interaction between plasmonic nanostructures and upconversion nanoparticles (UCNPs) is reported. The nanosensor is composed of a gold nanodisk and UCNPs separated by a flexible polymer layer. The gold nanodisk is designed to exhibit a plasmon resonance that selectively enhances one of the emission bands of the UCNPs while leaving the other ones largely unaffected. As the nanosensor is compressed or stretched by an external force, the polymer layer thickness changes, modulating the plasmon‐UCNP coupling. The resulting changes in the luminescence intensity provide the basis for sensing. Furthermore, the nanosensor employs ratiometric sensing, which makes it highly robust against any environmental variations. The nanosensors exhibit two orders of magnitude higher responsivity than previously reported UCNP‐based force sensors. They can be prepared as an on‐chip sensor array or in a colloidal solution, making them suitable for a variety of applications in biology and robotics. 

A new nanofabrication approach is reported for the scalable production of plasmonically modulated upconverting nanoparticles, with the potential for force sensing. 

We have developed a versatile transition metal-free cross-coupling reaction between fluorinated benzyl electrophiles and alkenylboronic acids in the presence of the equivalent amount of alkali metal salts such as K 3 PO 4 . This transition metal-free protocol gives good chemical yields for a wide range of substrates and demonstrates good functional group tolerance.